What are the negative electrode materials for lithium ion batteries? Introduction of cathode materials for lithium ion batteries
The negative electrode of lithium-ion battery is made of carbon or non-carbon materials, adhesives and additives, which are mixed to make a paste adhesive evenly coated on both sides of the copper foil, and then dried and rolled. The cathode material is the main body of lithium-ion battery to store lithium, which makes lithium ions embedded and removed in the process of charging and discharging. From a technical point of view, the cathode materials of lithium-ion batteries will show diversity in the future.
With the progress of technology, the current anode materials for lithium-ion batteries
have developed from a single artificial graphite to a situation in
which natural graphite, mesophase carbon microsphere and artificial
graphite are the main anode materials, and soft carbon / hard carbon,
amorphous carbon, lithium titanate, silicon carbon alloy and other anode
materials coexist.
Anode
material: mostly graphite. New research finds that titanate may be a
better material. Negative electrode reaction: lithium ion insertion
during charging and lithium ion de insertion during discharging.
Charging: xli++ xe-+ 6C → lixc6 discharging: lixc6 → xli++ xe-+ 6C
There are about six kinds of cathode materials for lithium-ion batteries:
carbon cathode materials, alloy cathode materials, tin based cathode
materials, lithium containing transition metal nitride cathode
materials, nano materials and nano cathode materials.
The
first is carbon anode materials: the anode materials actually used in
lithium-ion batteries are basically carbon materials, such as artificial
graphite, natural graphite, mesophase carbon microspheres, petroleum
coke, carbon fiber, pyrolytic resin carbon, etc.
The
second is tin based anode materials: tin based anode materials can be
divided into tin oxide and tin based composite oxide. Oxide refers to
the oxide of various valence metal tin. No commercial products.
The third is lithium containing transition metal nitride cathode material, which has no commercial products.
The
fourth is alloy negative electrode materials, including tin based
alloys, silicon-based alloys, germanium based alloys, aluminum based
alloys, antimony based alloys, magnesium based alloys and other alloys.
There are no commercial products.
The fifth is nano scale anode materials: carbon nanotubes and nano alloy materials.
The
sixth kind of nano material is nano oxide material: according to the
latest market development trend of lithium battery new energy industry
in 2009, many companies have begun to use nano titanium oxide and nano
silicon oxide to add to the previous traditional graphite, tin oxide and
carbon nanotubes, greatly improving the charging and discharging power
and charging and discharging times of lithium batteries.
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